National Highway 65 connects Ambala in Haryana with Pali in Rajasthan. This 690 km road starts from the junction of Grand Trunk Road and
National Highway 22 at Ambala. It then traverse south-west for 250 km before entering Rajasthan at Jhumpa; Kaithal, Narwana, Barwala and Hissar are some major towns that lie along the National Highway 65 on the Haryana side.
In Rajasthan, the road passes through Rajgarh, Jhunjhunu, Nagaur and Jodhpur before terminating at Pali, 30 km south-east of Rohat.